矿物作为地球系统的一种基本组成单元和环境要素，不仅是人类赖以生存和发展的物质基础，也是人类掌握地球环境演化规律的重要介质。由于矿物在岩石圈、水圈、生物圈乃至大气圈广泛存在，基于矿物的环境科学与工程研究对于理解地球环境变迁以及治理环境污染具有重要作用。

将储量（或产量）巨大、成本低廉的矿物资源及其二次资源用于污染控制、实现碳减排乃至“碳中和”，不仅是人类高效利用资源的长期需求，更是人类保持地球宜居性、实现可持续发展的现实要求。尤为紧迫的是，要实现《巴黎协定》提出的气温控制目标和我国的“2060年碳中和”承诺，积极研发包括“矿物法”在内的碳中和技术（二氧化碳矿物化封存、矿物增效的生物泵等）刻不容缓。

此外，人类未来还将走出地球；而太空移民需要评估行星宜居性并改造其人居环境。因而，前瞻性地开展行星矿物资源及其环境效应研究具有现实意义。

着眼于上述背景，本团队面向“碳中和-碳减排”和“矿物低碳高效利用”，秉持“利用矿物资源治理环境”的理念，运用环境矿物学、应用矿物学、碳中和矿物学、地质微生物学和表界面物理化学等学科的研究方法，开展基于矿物的碳中和-碳减排理论及其应用、低值/二次/新兴矿物资源的低碳高效利用、矿物基环境材料和应用等研究，以期为我国实现碳中和-碳减排乃至可持续发展目标提供有力支撑。

研究方向

 （1）“矿物法固碳”的理论和方法。矿物-固碳微生物之界面作用的固碳增效机制和应用；表生环境中矿物-有机质复合体的固碳效应和机制；基于低值矿物资源的绿色建材研制和应用；用于碳捕捉、利用和封存（CCUS）的矿物材料研制和应用。

（2）矿物及其二次资源的低碳高效利用和污染控制。针对富含矿物相的二次矿产资源、工业固体废弃物、城市二次资源，研究矿物及其二次资源的低碳高效利用与衍生污染的控制机理和应用。

（3）我国特色和新兴矿物资源、海洋和行星矿物资源的环境效应和应用。基于我国特色高活性矿物原料的环境功能材料、污染控制材料研制与应用；海洋和行星矿物的资源环境效应调控及其应用。

 

团队成员

团队负责人：袁鹏教授。

团队成员：卜红玲副教授、庄官政副教授、张佰发博士。

…… 新成员招募中（详见本团队诚聘青年人才公告）。

 

科研项目

曾承担国家高层次人才特殊支持计划领军人才项目、国家自然科学基金项目（12项）以及科技部、中科院、广东省的科研课题逾30项。

 

近年的代表性论著

学术专著

       Yuan P., Bergaya F., Thill A. Nanosized Tubular Clay Minerals, Elsevier, 2016

 

共发表SCI收录论文逾200篇。近5年的代表性论文如下：

代表性论文

[1] Wei Yanfu, Yuan Peng, Liu Dong, Liu Mingxian, Losic Dusan, Ma Xiaomin, Jiang Ran, Wu Nanchun, Yang Fang, Zhang Junxiong. Converting Chrysotile Nanotubes into Magnesium Oxide and Hydroxide Using Lanthanum Oxycarbonate Hybridization and Alkaline Treatment for Efficient Phosphate Adsorption. Inorganic Chemistry [J]. 2022. https://doi.org/10.1021/acs.inorgchem.2c02052

[2] Zhang Baifa, Yu Ting, Deng Liangliang, Li Yun, Guo Haozhe, Zhou Junming, Li Lijuan, Yuan Peng.Ion-adsorption type rare earth tailings for preparation of alkali-based geopolymer with capacity for heavy metals immobilization. Cement and Concrete Composites [J]. 2022

[3] Li Li, Zhuang Guanzheng, Li Mengyuan, Yuan Peng, Deng Liangliang, Guo Haozhe. Influence of indigo-hydroxyl interactions on the properties of sepiolite-based Maya blue pigment. Dyes and Pigments [J]. 2022, 200, 110138. https://doi.org/10.1016/j.dyepig.2022.110138

[4] Zhou Junming, Liu Hongmei, Liu Dong, Yuan Peng, Bu Hongling, Du Peixin, Fan Wenxiao, Li Mengyuan. Sorption/desorption of Eu (III) on halloysite and kaolinite. Applied Clay Science [J]. 2022, 216, 106356. https://doi.org/10.1016/j.clay.2021.106356

[5] Zhong, Xuemin, Yuan Peng, Wei Yanfu, Liu Dong, Losic Dusan, Li Mengyuan. Coupling Natural Halloysite Nanotubes and Bimetallic Pt–Au Alloy Nanoparticles for Highly Efficient and Selective Oxidation of 5-Hydroxymethylfurfural to 2, 5-Furandicarboxylic Acid. ACS Applied Materials & Interfaces [J]. 2022, 14(3): 3949-3960. https://doi.org/10.1021/acsami.1c18788

[6] 袁鹏, 刘冬. 矿物增效的生物泵:基于矿物-微生物作用的水体CO₂增汇策略. 科学通报 [J]. 2022, 67(10): 924-932. https://doi: 10.1360/TB-2021-1267

[7] Zhuang Guanzheng, Li Li, Li Mengyuan, Yuan Peng.Influences of micropores and water molecules in the palygorskite structure on the color and stability of Maya blue pigment. Microporous and Mesoporous Materials [J]. 2022, 330, 111615. https://doi.org/10.1016/j.micromeso.2021.111615

[8] Zhong Xuemin, Wei Yanfu, Samahe Sadjadi, Liu Dong, Li Mengyuan, Yu Ting, Zhuang Guanzheng, Yuan Peng. Base-free oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid over palygorskite-supported bimetallic Pt–Pd catalyst. Applied Clay Science [J]. 2022, 226, 106574. https://doi.org/10.1016/j.clay.2022.106574

[9] Meng Fangyuan, Bu Hongling, Fei Yingheng, Chen Manjia, Lei Qinkai, Liu Dong, Hua Jian, Wu Fei, Liu Chengshuai. Effects of clay minerals on Fe²⁺-induced phase transformation of ferrihydrite. Applied Geochemistry [J]. 2022, 144, 105401. https://doi.org/10.1016/j.apgeochem.2022.105401

[10] Xu Wenpo, Liu Chengshuai, Zhu Jianming, Bu Hongling, Tong Hui, Chen Manjia, Tan Decan, Gao Ting, Liu Yizhang. Adsorption of cadmium on clay-organic associations in different pH solutions: The effect of amphoteric organic matter. Ecotoxicology and Environmental Safety [J]. 2022, 236, 113509. https://doi.org/10.1016/j.ecoenv.2022.113509

[11] Zhang Baifa, Yuan Peng, Guo Haozhe, Deng Liangliang, Li Yun, Li Li, Wang Qiang, Liu Dong. Effect of curing conditions on the microstructure and mechanical performance of geopolymers derived from nanosized tubular halloysite. Construction and Building Materials [J]. 2021, 268, 121186. https://doi.org/10.1016/j.conbuildmat.2020.121186.

[12] Guo Haozhe, Zhang Baifa, Deng Liangliang, Yuan Peng, Li Mengyuan, Wang Qiang. Preparation of high-performance silico-aluminophosphate geopolymers using fly ash and metakaolin as raw materials. Applied Clay Science [J]. 2021, 204, 106019. http://dx.doi.org/10.1016/j.clay.2021.106019.

[13] Guo Haozhe, Yuan Peng, Zhang Baifa, Wang Qiang, Deng Liangliang, Liu Dong.Realization of high-percentage addition of fly ash in the materials for the preparation of geopolymer derived from acid-activated metakaolin. Journal of Cleaner Production [J]. 2021, 285, 125430. http://dx.doi.org/10.1016/j.jclepro.2020.125430.

[14] Zhou Junming, Li Mengyuan, Yuan Peng, Li Yun, Liu Hongmei, Fan Wenxiao, Liu Dong, Zhang Huan. Partial rehydration of tubular halloysite (7 angstrom) immersed in La(NO₃)₃ solution for 3 years and its implication for understanding REE occurrence in weathered crust elution-deposited rare earth ores. Applied Clay Science [J]. 2021, 213, 106244. https://doi.org/10.1016/j.clay.2021.106244

[15] Yuan Peng, Liu Dong. Proposing a potential strategy concerning Mineral-enhanced Biological Pump (MeBP) for improving Ocean Iron Fertilization (OIF). Applied Clay Science [J]. 2021, 207, 106096. http://dx.doi.org/10.1016/j.clay.2021.106096.

[16] Liu Hongchang, Yuan Peng, Liu Dong, Zhang Weiwei, Tian Qian, Bu Hongling, Wei Yanfu, Xia Jinlan, Wang Yinchu, Zhou Junming. Insight into cyanobacterial preservation in shallow marine environments from experimental simulation of cyanobacteria-clay co-aggregation. Chemical geology [J]. 2021, 577, 120285. http://dx.doi.org/10.1016/j.chemgeo.2021.120285.

[17] Wei Longmei, Bu Hongling, Wei YanFu, Wu Honghai, Wang Gehui, Chen Pengcheng, Li Hongmei. Fractionation of natural algal organic matter and its preservation on the surfaces of clay minerals. Applied Clay Science [J]. 2021, 213, 106235. https://doi.org/10.1016/j.clay.2021.106235

[18] Zhang Baifa, Guo Haozhe, Yuan Peng, Deng Liangliang, Zhong Xuemin, Li Yun, Wang Qiang, Liu Dong. Novel acid-based geopolymer synthesized from nanosized tubular halloysite: The role of precalcination temperature and phosphoric acid concentration. Cement and Concrete Composites [J]. 2020, 110, 103601. https://doi.org/10.1016/j.cemconcomp.2020.103601

[19] Li Yun, Chen Meng, Song Hongzhe, Yuan Peng, Liu Dong, Zhang Baifa, Bu Hongling. Methane hydrate formation in the stacking of kaolinite particles with different surface contacts as nanoreactors: A molecular dynamics simulation study. Applied Clay Science [J]. 2020, 186, 105439. http://dx.doi.org/10.1016/j.clay.2020.105439.

[20] Song Yaran, Yuan Peng, Du Peixin, Deng Liangliang, Wei Yanfu, Liu Dong, Zhong Xuemin, Zhou Junming. A novel halloysite-CeOx nanohybrid for efficient arsenic removal. Applied Clay Science [J]. 2020, 186, 105450. http://dx.doi.org/10.1016/j.clay.2020.105450.

[21] 袁鹏.铝硅酸盐纳米矿物——亟待重视的地球物质循环载体和非传统矿产资源.科学观察[J]. 2020, 15(6), 71-74, http://lib.cqvip.com/Qikan/Article/Detail?id=7103761404.

[22] Wang Shun, Du Peixin, Yuan Peng, Liu Yaqi, Song Hongzhe, Zhou Junming, Deng Liangliang, Liu Dong. Structural alterations of synthetic allophane under acidic conditions: Implications for understanding the acidification of allophanic Andosols. Geoderma [J]. 2020, 376, 114561. http://dx.doi.org/10.1016/j.geoderma.2020.114561.

[23] Li Yun, Chen Meng, Song Hongzhe, Yuan Peng, Zhang Baifa, Liu Dong, Zhou Huijun, Bu Hongling. Effect of cations (Na⁺, K⁺, and Ca²⁺) on methane hydrate formation on the external surface of montmorillonite: insights from molecular dynamics simulation. ACS Earth and Space Chemistry [J]. 2020, 4(4), 572-582. https://doi.org/10.1021/acsearthspacechem.9b00323

[24] Du Peixin, Thill Antoine, Yuan Peng, Wang Shun, Liu Dong, Gobeaux Frédéric, Deng Liangliang, Song Yaran. Tailoring structure and surface chemistry of hollow allophane nanospheres for optimization of aggregation by facile methyl modification. Applied Surface Science [J]. 2020, 510, 145453. http://dx.doi.org/10.1016/j.apsusc.2020.145453.

[25] Deng Liangliang, Liu Yaqi, Zhuang Guanzheng, Yuan Peng, Liu Dong, Bu Hongling, Song Hongzhe, Li Li. Dynamic benzene adsorption performance of microporous TMA⁺-exchanged montmorillonite: the role of TMA+ cations. Microporous and Mesoporous Materials [J]. 2020. 296, 109994. https://doi.org/10.1016/j.micromeso.2019.109994

[26] Li Yun, Chen Meng, Liu Chanjuan, Song Hongzhe, Yuan Peng, Zhang Baifa, Liu Dong, Du Peixin. Effects of layer-charge distribution of 2: 1 clay minerals on methane hydrate formation: a molecular dynamics simulation study. Langmuir[J]. 2020. 36(13), 3323-3335. https://doi.org/10.1021/acs.langmuir.0c00183

[27] Du Peixin, Yuan Peng, Liu Jiacheng, Yang Yixuan, Bu Hongling, Wang Shun, Zhou Junming, Song Hongzhe, Liu Dong, Michalski, Joseph R, Liu Chengshuai. Effects of Environmental Fe Concentrations on Formation and Evolution of Allophane in Al‐Si‐Fe Systems: Implications for Both Earth and Mars. Journal of Geophysical Research: Planets [J]. 2020, 125(12), e2020JE006590. https://doi.org/10.1029/2020JE006590

[28] Bu Hongling, Liu Dong, Yuan Peng, Zhou Xiang, Liu Hongmei, Song Hongzhe, Zhang Baifa. Ethylene glycol monoethyl ether adsorption by interlayer montmorilonite-organic matter complexes: Dependence on the organic matter content and its alkyl chain length. Applied Clay Science[J]. 2019. 180, 105190. https://doi.org/10.1016/j.clay.2019.105190

[29] Bu Hongling, Liu Dong, Yuan Peng, Zhou Xiang, Liu Hongmei, Du Peixin. Ethylene glycol monoethyl ether (EGME) adsorption by organic matter (OM)-clay complexes: dependence on the OM Type. Applied Clay Science [J]. 2019, 168, 340-347. https://doi.org/10.1016/j.clay.2018.11.026

[30] Song Yaran, Yuan Peng, Wei Yanfu, Liu Dong, Tian Qian, Zhou Junming, Du Peixin, Deng Liangliang, Chen Fanrong, Wu Honghai. Constructing hierarchically porous nestlike Al₂O₃–MnO₂@ Diatomite composite with high specific surface area for efficient phosphate removal. Industrial & Engineering Chemistry Research [J]. 2019, 58(51), 23166-23174. https://doi.org/10.1021/acs.iecr.9b05574

[31] Liu Dong, Yuan Peng, Tian Qian, Liu Hongmei, Deng Liangliang, Song Yaran, Zhou Junming, Losic Dusan, Zhou Jieyu, Song Hongzhe, Guo Haozhe, Fan Wenxiao. Lake sedimentary biogenic silica from diatoms constitutes a significant global sink for aluminium. Nature communications [J]. 2019, 10(1), 1-7. https://doi.org/10.1038/s41467-019-12828-9

[32] Deng Liangliang, Du Peixin, Yu Wenbin, Yuan Peng, FaïzaAnnabi-Bergaya, Liu Dong, Zhou Junming. Novel hierarchically porous allophane/diatomite nanocomposite for benzene adsorption. Applied Clay Science [J]. 2019, 168, 155-163. http://dx.doi.org/10.1016/j.clay.2018.11.007.

[33] Deng Liangliang, Yuan Peng, Liu Dong, Du Peixin, Zhou Junming, Wei Yanfu, Song Yaran, Liu Yaqi. Effects of calcination and acid treatment on improving benzene adsorption performance of halloysite. Applied Clay Science [J]. 2019, 181, 105240. http://dx.doi.org/10.1016/j.clay.2019.105240.

[34] Liu Dong, Tian Qian, Yuan Peng, Du Peixin, Zhou Junming, Li Yun, Bu Hongling, Zhou Jieyu. Facile sample preparation method allowing TEM characterization of the stacking structures and interlayer spaces of clay minerals. Applied Clay Science [J]. 2019, 171, 1-5. http://dx.doi.org/10.1016/j.clay.2019.01.019.

[35] Wei Yanfu, Yuan Peng, Liu Dong, Losic Dusan, Tan Daoyong, Chen Fanrong, Liu Hongchang, Zhou Junming, Du Peixin, Song Yaran. Activation of natural halloysite nanotubes by introducing lanthanum oxycarbonate nanoparticles via co-calcination for outstanding phosphate removal. Chemical communications [J]. 2019, 55(14), 2110-2113. https://doi.org/10.1039/C8CC10314C

[36] Yuan Peng, Liu Dong, Zhou Junming, Tian Qian, Song Yaran, Wei Huihuang, Wang Shun, Zhou Jieyu, Deng Liangliang and Du Peixin. Identification of the occurrence of minor elements in the structure of diatomaceous opal using FIB and TEM-EDS. American Mineralogist [J]. 2019, 104(9), 1323-1335. https://doi.org/10.2138/am-2019-6917

[37] Bu Hongling, Yuan Peng, Liu Hongmei, Liu Dong, Qin Zonghua, Zhong Xuemin, Song Hongzhe, Li Yun. Formation of macromolecules with peptide bonds via the thermal evolution of amino acids in the presence of montmorillonite: Insight into prebiotic geochemistry on the early Earth. Chemical Geology [J]. 2019, 510, 72-83. http://dx.doi.org/10.1016/j.chemgeo.2019.02.023.

[38] Zhou Xiang, Liu Dong, Bu Hongling, Deng Liangliang, Liu Hongmei, Yuan Peng, Du Peixin, Song Hongzhe. XRD-based quantitative analysis of clay minerals using reference intensity ratios, mineral intensity factors, Rietveld, and full pattern summation methods: A critical review. Solid Earth Sciences [J]. 2018, 3(1), 16-29. https://doi.org/10.1016/j.sesci.2017.12.002

[39] 袁鹏. 纳米结构矿物的特殊结构和表-界面反应性. 地球科学 [J]. 2018, 43(05), 1384-1407. http://doi.org/10.3799//dqkx.2018.533

[40] Bu Hongling, Yuan Peng, Liu Hongmei, Liu Dong, Liu Jinzhong, He Hongping, Zhou Junming, Song Hongzhe, Li Zhaohui. Effects of complexation between organic matter (OM) and clay mineral on OM pyrolysis. Geochimica et Cosmochimica Acta [J]. 2017, 212, 1-15. https://doi.org/10.1016/j.gca.2017.04.045.

 

近年获得授权的发明专利

共获得中国发明专利授权逾30件。近年的主要发明专利如下：

袁鹏，等；一种双金属合金-埃洛石复合物及其制备方法和应用，专利号：ZL202010753808.2.

袁鹏，等；一种用于吸附有机气体的埃洛石-沸石复合材料及其制备方法，专利号：ZL202011242170.2.

袁鹏，等；一种用于吸附有机气体的水铝英石材料及其制备方法，专利号：ZL201811560843.1

袁鹏，等；一种具有多级孔道结构的硅藻土/水铝英石复合材料及其制备方法，专利号：ZL201811006254.9

袁鹏，等；一种吸附挥发性有机物的多级孔道结构蜂窝体及其制备方法，专利号：ZL201611168572.6

庄官政，等；制备有机插层型蒙脱石的半干法，专利号：ZL201310219527.9

庄官政，等；阴-阳离子型有机粘土在油基钻井液中的应用，专利号：ZL201510236423.8；

庄官政，等；一种新型油基钻井液用有机海泡石及其制备方法，专利号：ZL201710236093.1

庄官政，等；一种海泡石提纯和有机改性的一步法工艺，专利号：ZL201710317168.9

庄官政，等；一种油基钻井液用复合有机粘土及其复配方法，专利号：ZL201810060193.8

 

标志性成果

   （1）发现湖泊沉积的硅藻生物硅是地球重要铝汇；提出“矿物增效生物泵固碳（MeBP）”理论假说。

成果发表于Nature Communications、Applied Clay Science、American Mineralogist、《科学通报》等。

   （2）发现典型纳米矿物（埃洛石、水铝英石和伊毛缟石）和纳米结构矿物（硅藻蛋白石、蒙脱石和高岭石等）及其衍生物的系列特殊精细结构；阐释了特定表生环境中矿物对有机质和稀土等迁移、富集和归趋的制约机制；系统提出了定向调控纳米矿物的结构和表-界面反应性的方法。

   成果发表于Geochimica et Cosmochimica Acta、Chemical Communications、Journal of Hazardous Materials、Inorganic Chemistry、Geoderma等期刊；论文的最高单

   篇 SCI引用逾700次；在Elsevier出版英文学术专著1部。